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Activity (Hands-On)Grades 9 - 12

Soap vs. Shampoo Surfactant Lab

A cutaway diagram of a liquid depicts a few molecules in its mass and at its surface. Arrows around those in the liquid indicate forces equally around the molecules, compared to arrows around molecules at the surface, showing forces from the water sides, but not the air sides.Surface tension results from the molecules at the surface experiencing larger attractive forces toward the liquid than towards the air.

Students learn about the properties of solutions—such as ion interactions, surface tension and viscosity—as they make their own soap and shampoo and then compare their properties. Working as if they are chemical engineers, they explore and compare how the two surfactants behave in tap water, as well as classroom-prepared acidic water, hard water and seawater using four tests: a “shake test” (assessing the amount of bubbles produced), a surface tension test, a viscosity test, and a pH test. Then they coalesce their findings into a recommendation for how to engineer the best soap versus shampoo. The activity may be shortened by using purchased liquid soap and shampoo from which students proceed to conduct the four tests. A lab worksheet and post-quiz are provided.

Chemical engineers in the soap industry must have a clear understanding of the topics explored in this activity—including pH, viscosity, surface tension and ion interactions—in order to design surfactants for specific applications, ranging from soaps and shampoos to detergents. In this activity, students engineer soaps and shampoos and test their surfactants in different types of water. Similarly, chemical engineers systematically test their designs before making the products ready for the consumer market.

After this activity, students should be able to:

  • Describe surfactant behavior in tap water, hard water, salt water and acidic water.
  • Compare and contrast soap and shampoo properties.
  • Describe surface tension and viscosity.

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